1-(1-Adamantylcarbonyl)proline (ACA) ikora ifu No. ya CAS: 35084-48-1 98% ubuziranenge bw'ibicuruzwa by'inyongera
Videwo y'ibicuruzwa
Ibipimo by'ibicuruzwa
| Izina ry'igicuruzwa | Proline ya 1-(1-Adamantylcarbonyl) |
| Irindi zina | 1-(1-ADAMANTYLCARBONYL)PYRROLIDINE-2-ACID YA KABOKISILIKE; 1- (ADAMANTANE-1-KABONYL)-PYRROLIDINE-2-ASIDE YA KABOXYLIKE; 1-(1-Adamantylcarbonyl)proline; L-Proline, 1-(tricyclo[3.3.1.13,7]dec-1-ylcarbonyl)- |
| Nimero ya CAS | 35084-48-1 |
| Ifishi y'ingirabuzimafatizo | C16H23NO3 |
| Uburemere bwa molekile | 277.36 |
| Ubwiza | 98.0% |
| Isura | Ifu y'umweru |
| Gupakira | 1kg/umufuka 10kg/ingoma 25kg/ingoma |
| Porogaramu | Nootropic |
Intangiriro y'ibicuruzwa
Proline ya 1-(1-Adamantylcarbonyl) ni ikintu kiva kuri phenylalanine, kizwi kandi nka adamantylproline cyangwa Ad-Pro. Ikoreshwa cyane cyane nk'ingufu cyangwa ingirabuzimafatizo za chiral mu guhuza ibinyabuzima. Ubushakashatsi bwagaragaje ko proline ya 1-(1-Adamantylcarbonyl) ishobora gukurura ingaruka z'inyongera za nucleophilic zitagira ingano, nko gukora kwa aldehydes na alkylene azides, gukora kwa aldehydes na sulfuryl folate, gukora kwa aldehydes na nitro Methane, nibindi. Muri izi ngaruka, iyi catalyst ifite imbaraga zo kongeramo aldehydes za alkylene. Proline ya 1-(1-Adamantylcarbonyl) ishobora kandi gukurura ingaruka z'inyongera zitagira ingano. Proline ya 1-(1-Adamantylcarbonyl) ishobora kandi gukoreshwa nk'ingufu za chiral mu gutera alcoolisation itagira ingano. Urugero, ishobora gutera alcool hamwe na aldehydes cyangwa ketones kugira ngo itange umusaruro wa aldol cyangwa hydroxyketone. Proline ya 1-(1-Adamantylcarbonyl), nk'ikintu cy'umwimerere cya chiral, ifite imikorere myiza cyane ya catalytic.
Ikiranga
(1) 1-(1-Adamantylcarbonyl) proline ni ifu yera cyangwa idasembuye neza kandi irashongesha neza. Ifite ubushobozi buke bwo gushonga mu mazi ariko akenshi ishongesha neza mu bintu bishongesha bikomoka ku bimera. Ni ikintu kidahinduka gishobora kubikwa ku bushyuhe bw'icyumba igihe kirekire.
(2) 1-(1-Adamantylcarbonyl) proline ni molekile ya chiral ifite enantiomeri ebyiri. Imiterere yayo ya chiral ituma ikoreshwa cyane mu guhuza chiral. Muri rusange, isomer imwe ya chiral ni yo igomba gukoreshwa kubera ko ifite induction nziza ya chiral.
(3) Ubuziranenge bukabije: 1-(1-Adamantylcarbonyl) proline ishobora kubona ibicuruzwa bifite ubuziranenge buhanitse binyuze mu gutunganya umusaruro. Ubuziranenge buhanitse busobanura ko binyabuzima biboneka neza kandi ingaruka mbi zikaba nke.
(4) Guhagarara: 1-(1-Adamantylcarbonyl) proline ifite ubushobozi bwo kugumana imikorere n'ingaruka zayo mu bidukikije bitandukanye no mu buryo butandukanye bwo kubika.
Porogaramu
Proline ya 1-(1-Adamantylcarbonyl) ni ifu y’umwimerere irimo azote, ifu yera cyangwa idafite umweru, ikoreshwa nk'igice cy’ingenzi n'ibindi bikorwa mu buvuzi. Byongeye kandi, bitewe n'imiterere yayo yihariye ya chiral, ikoreshwa cyane mu guhuza chiral organic, harimo asymmetric nucleophilic addition reactions, amination reactions, alcoholization reactions, nibindi.
